The match will take place at the 33,000-seat Cardiff City Stadium. It will start at 19:00 Kyiv time.
Earlier, Ukraine beat Scotland 3:1 and Wales saw off Austria 2:1 in the play-off semi-finals.
The winner of Sunday's play-off final will face England, USA, and Iran in Group B.
2022 FIFA World Cup is scheduled to take place in Qatar from 21 November to 18 December 2022.
Let’s get started read our news at facebook messenger > > > Click here for subscribe