The match took place at the Alfredo di Stefano training ground in Madrid on October 21. The Ukrainian club raced into a 3-0 lead after the first half of the match.
In another Group B game, Italy's Inter and Germany's Borussia Monchengladbach played out a 2-2 draw at the Giuseppe Meazza stadium in Milan.
Shakhtar will play their next game against Inter in Kyiv on October 27.
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