The match took place at the Arena Lviv on Monday, June 10. Ukraine forward Roman Yaremchuk scored the only goal in the sixth minute.
In another match of the qualifying Group B, Serbia beat Lithuania 4-1 in Belgrade.
Ukraine will play its next game against Lithuania in Vilnius on September 7.
Ukraine currently tops its group with ten points from four games, followed by Luxembourg (four points from four games), Serbia (four points from three games), Portugal (two points from two games), and Lithuania (one point from three games).
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